呼延成副研究员-仿生催化合成研究组

呼延成（Yan-Cheng Hu）

Associate Research Fellow

Dalian Institute of Chemical Physics,
Chinese Academy of Sciences,
457 Zhongshan Road, Dalian 116023, P. R. China
Tel: 86-411-84771230 (office)
E-mail: ychu@dicp.ac.cn

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Educational Background

2019.7—2022.6, Associate Research Fellow, Dalian Institute of Chemical Physics, CAS.
2018.1—2019.7, Assistant Research Fellow, Dalian Institute of Chemical Physics, CAS.
2015.7—2018.1, Post-doctoral researcher in the group of Prof. Tao Zhang, Dalian Institute of Chemical Physics, CAS.
2011.9—2015.7, Ph. D. in Organic Chemistry, Advisor Prof. Bo-Shun Wan, Dalian Institute of Chemical Physics, CAS.
2010.9—2011.7, Graduate Course, University of Science and Technology of China.
2006.9—2010.7, B.S. in Chemistry, Nanjing Normal University.

Awards

Representative Publications

37. Wei-Nan Zhang, Yan-Cheng Hu, Yan Liu, Xiao-Yu Wang, Ying-Ying Zhao,* and Qing-An Chen.* Ligand-controlled regiodivergence in Pd-catalyzed coupling of azlactones with isoprene. Cell Rep. Phys. Sci. 2024, 5, 101908.

36. Ying Li, Wei-Song Zhang, Shao-Han Sun, Yong-Kang Mei, Ding-Wei Ji, Yan-Cheng Hu,* and Qing-An Chen.* Nickel-Catalyzed Hydrobivinylation of Enones with 1,3-Dienes. Cell Rep. Phys. Sci. 2023, 4, 101602.

38. Hao Zheng, Chang-Hui Liu, Xiao-Yu Wang, Yan Liu, Bing-Zhi Chen, Yan-Cheng Hu,* and Qing-An Chen.* Catalytic Undirected Meta-Selective C–H Borylation of Metallocenes. Adv. Sci. 2023, 2304672.

37. Heng Liu, Ding-Wei Ji, Xiang-Ting Min, Yong-Kang Mei, Shao-Han Sun, Gong Zhang, Yan-Cheng Hu, and Qing-An Chen.* Disproportionation-Inspired Construction of Highly Functionalized Bicyclo[3.2.1]octanes. Org. Lett. 2023, 25, 1878-1882.

36. Ding-Wei Ji, Yan-Cheng Hu, Xiang-Ting Min, Heng Liu, Wei-Song Zhang, Ying Li, Yongjin J. Zhou, and Qing-An Chen.* Skeleton-Reorganizing Coupling Reactions of Cyclohepta-triene and Cycloalkenones with Amines. Angew. Chem. Int. Ed. 2023, 62, e202213074.

35. Gong Zhang, Chao-Yang Zhao, Xiang-Ting Min, Ying Li, Xiang-Xin Zhang, Heng Liu, Ding-Wei Ji, Yan-Cheng Hu, Qing-An Chen.* Nickel-Catalysed Asymmetric Heteroarylative Cyclotelomerization of Isoprene. Nature Catalysis 2022, 5, 708-715.

34. Xiang-Ting Min, Yong-Kang Mei, Bing-Zhi Chen, Li-Bowen He, Ting-Ting Song, Ding-Wei Ji, Yan-Cheng Hu, Boshun Wan, Qing-An Chen.* Rhodium-Catalyzed Deuterated Tsuji-Wilkinson Decarbonylation of Aldehydes with Deuterium Oxide. J. Am. Chem. Soc. 2022, 44, 11081-11087.

33. Chao-Yang Zhao, Ying-Ying Liu, Xiang-Xin Zhang, Gu-Cheng He, Heng Liu, Ding-Wei Ji, Yan-Cheng Hu, Qing-An Chen.* Bioinspired and Ligand-Regulated Unnatural Prenylation and Geranylation of Oxindoles with Isoprene under Pd Catalysis. Angew. Chem. Int. Ed. 2022, 61, e202207202.

32. Lei-Lei Qian, Yan-Cheng Hu,* Xiang-Ting Min, Sa-Na Yang, Bing-Xue Shen, Boshun Wan, Qing-An Chen.* CPA-Catalyzed Multicomponent Reaction of Anilines, Aldehydes, and Azetidinones: Rapid Access to Enantiopure Fused Azetidines. Chem Catalysis. 2022, 2, 2024-2033.

31. Xin Huang,^† Bing-Zhi Chen,^†Pengbin Li, Ding-Wei Ji, Jinxian Liu,Hao Zheng, Sa-Na Yang, Yan-Cheng Hu, Boshun Wan, Xiang-Ping Hu, Chunling Fu, Yankai Huang, Jian Zheng,* Qing-An Chen,* Shengming Ma.* Palladium-catalyzed construction of butafulvenes. Nature Chemistry 2022, 14, 1185-1192.

30. Hao Zheng, Chang-Hui Liu, Shi-Yu Guo, Gu-Cheng He, Xiang-Ting Min, Bo-Chao Zhou, Ding-Wei Ji, Yan-Cheng Hu, Qing-An Chen.* Regioselective C−H Phosphorylation of Group 8 Metallocenes under Electrochemical Autocatalysis. Nature Communications 2022, 13, 3496.

29. Yan-Cheng Hu, Xiang-Ting Min, Ding-Wei Ji, Qing-An Chen.* Catalytic Prenylation and Reverse-Prenylation of Aromatics. Trends in Chemistry 2022, 4, 658-675.

28. Wei-Song Zhang, Ding-Wei Ji, Ying Li, Xiang-Xin Zhang, Chao-Yang Zhao, Yan-Cheng Hu and Qing-An Chen.* Regio- and Stereoselective Diarylation of 1,3-Dienes via Ni/Cr Co-catalysis. ACS Cat. 2022, 12, 2158-2165.

28. Shi-Yu Guo, Fan Yang, Ting-Ting Song, Yu-Qing Guan, Xiang-Ting Min, Ding-Wei Ji, Yan-Cheng Hu and Qing-An Chen.* Photo-Induced Catalytic Halopyridylation of Alkenes. Nature Communications 2021, 12, 6538.

27. Heng Liu, Gu-Cheng He, Chao-Yang Zhao, Xiang-Xin Zhang, Ding-Wei Ji, Yan-Cheng Hu and Qing-An Chen.* Redoxdivergent Construction of (Dihydro)thiophenes with DMSO. Angew. Chem. Int. Ed. 2021, 60, 24284-24291.

26. Yu-Qing Guan, Xiang-Ting Min, Gu-Cheng He, Ding-Wei Ji, Shi-Yu Guo, Yan-Cheng Hu and Qing-An Chen.* The Serendipitous Effect of KF in Ritter Reaction: Photo-Induced Amino-Alkylation of Alkenes. iScience 2021, 24, 102969.

25. Yan-Cheng Hu⁺, Ying Li⁺, Ding-Wei Ji, Heng Liu, Hao Zheng, Gong Zhang, Qing-An Chen.* Catalytic C2 prenylation of unprotected indoles: Late‐stage diversification of peptides and two-step total synthesis of tryprostatin B. Chin. J. Catal 2021, 42, 1593-1607.

24. Chao-Yang Zhao, Ding-Wei Ji, Hao Zheng, Gu-Cheng He, Heng Liu, Yan-Cheng Hu, and Qing-An Chen.* Pd-Catalyzed Redox Divergent Coupling of Ketones with Terpenols. ACS Cat. 2021, 11, 6825-6834.

23. Wen-Shuang Jiang⁺, Ding-Wei Ji⁺, Wei-Song Zhang, Gong Zhang, Xiang-Ting Min, Yan-Cheng Hu, Xu-Liang Jiang*, and Qing-An Chen.* Orthogonal Regulation of Nucleophilic and Electrophilic Sites in Pd-Catalyzed Regiodivergent Couplings between Indazoles and Isoprene. Angew. Chem. Int. Ed. 2021, 60, 8321-8328.

22. Yan-Cheng Hu⁺, Yingying Zhao⁺, Boshun Wan*, Qing-An Chen.* Reactivity of Ynamides in Catalytic Intermolecular Annulations. Chem. Soc. Rev. 2021, 50, 2582-2625.

21. Xiang-Ting Min, Ding-Wei Ji, Yu-Qing Guan, Shi-Yu Guo, Yan-Cheng Hu, Boshun Wan, Qing-An Chen.* Visible Light-Induced Bifunctional Rhodium Catalysis for Decarbonylative Coupling of Imides with Alkynes. Angew. Chem. Int. Ed. 2021, 60, 1583-1587.

20. Bing-Xue Shen, Xiang-Ting Min, Yan-Cheng Hu*, Lei-Lei Qian, Sa-Na Yang, Boshun Wan and Qing-An Chen. Copper-catalyzed boroacylation of allenes to access tetrasubstituted vinylboronates. Org. Biomol. Chem. 2020, 18, 9253-9260.

19. Chang-Sheng Kuai⁺, Ding-Wei Ji⁺, Chao-Yang Zhao, Heng Liu, Yan-Cheng Hu, Qing-An Chen.* Ligand Regulated Regiodivergent Hydrosilylation of Isoprene under Iron Catalysis. Angew. Chem. Int. Ed. 2020, 59,19115-19120.

18. Ding-Wei Ji, Fan Yang, Bing-Zhi Chen, Xiang-Ting Min, Chang-Sheng Kuai, Yan-Cheng Hu, Qing-An Chen.* Rhodium-catalyzed regio- and enantioselective allylic alkylation of pyrazol-5-ones with alkynes. Chem. Commun. 2020, 56, 8468-8471.

17. Wei-Song Zhang, Yan-Cheng Hu, Qing-An Chen.* Isoprene: A Promising Coupling Partner in C‒H Functionalizations. SynLett. 2020, 31, 1649-1655.

16. Leilei Qian⁺, Ruxia Yi⁺, Xiang-Ting Min, Yan-Cheng Hu, Boshun Wan,* Qing-An Chen.* Rapid assembly of 3-azidomethylfurans from 2-(1-alkynyl)-2-alken-1-ones enabled by silver catalysis. Tetrahedron. 2020, 76, 131327-131333.

15. Ding-Wei Ji, Gu-Cheng He, Wei-Song Zhang, Chao-Yang Zhao, Yan-Cheng Hu, Qing-An Chen.* Nickel-catalyzed allyl-allyl coupling reactions between 1,3-dienes and allylboronates. Chem. Commun. 2020, 56, 7431-7434.

14. Chao-Yang Zhao, Hao Zheng, Ding-Wei Ji, Xiang-Ting Min, Yan-Cheng Hu, and Qing-An Chen.* Copper-Catalyzed Asymmetric Carboboronation of Allenes to Access α-Quaternary Amino Esters with Adjacent Stereocenters. Cell Rep. Phys. Sci., 2020, 1, 100067.

13. Xiang-Ting Min, Ding-Wei Ji, Hao Zheng, Bing-Zhi Chen, Yan-Cheng Hu, Boshun Wan and Qing-An Chen.* Cobalt-Catalyzed Regioselective Carboamidation of Alkynes with Im-ides Enabled by Cleavage of C−N and C−C Bonds, Org. Lett. 2020, 22, 3386-3391.

12. Lei-Lei Qian, Xiang-Ting Min, Yan-Cheng Hu, Bing-Xue Shen, Sa-Na Yang, Boshun Wan and Qing-An Chen.* Ruthenium(ii)-catalyzed intermolecular annulation of alkenyl sulfonamides with alkynes: access to bicyclic sultams. Chem. Commun. 2020, 56, 2614-2617.

11. Ying Li⁺, Yan-Cheng Hu⁺, Ding-Wei Ji, Wei-Song Zhang, Gu-Cheng He, Yu-Feng Cong,* Qing-An Chen.* Acid-Catalyzed Chemoselective C- and O-Prenylation of Cyclic 1,3-Diketones. Chin. J. Catal 2020, 41, 1401-1409.

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10. Ying Li, Yan-Cheng Hu, Hao Zheng, Ding-Wei Ji, Yu-Feng Cong, Qing-An Chen.* Acid-Catalyzed Regiodivergent Annulation of 4-Hydroxycoumarins with Isoprene: Entry to Pyranocoumarins and Pyranochromones. Eur. J. Org. Chem 2019, 6510-6514.

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9. Jun Yang, Ding-Wei Ji, Yan-Cheng Hu, Xiang-Ting Min, Xiang-Ge Zhou,* Qing-An Chen.* Cobalt-Catalyzed Hydroxymethylarylation of Terpenes with Formaldehyde and Arenes. Chem. Sci. 2019, 10, 9560-9564.

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8. Ding-Wei Ji, Yan-Cheng Hu, Hao Zheng, Chao-Yang Zhao, Qing-An Chen* and Vy M. Dong. Catalytic Regioselectivity Switch in Pd-Catalyzed Hydroallylation of Alkynes. Chem. Sci. 2019 ,10, 6311-6315.

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7. Yan-Cheng Hu, Ding-Wei Ji, Chao-Yang Zhao, Hao Zheng, Qing-An Chen.* Catalytic Prenylation and Reverse-Prenylation of Indoles with Isoprene: Regioselectivity Manipulation by Metal-Hydride. Angew. Chem. Int. Ed. 2019, 58, 5438–5442.

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6. Yancheng Hu^#, Lin Yuan^#, Xiuli Zhang^#, Han Zhou, Pan Wang, Guangyi Li, Aiqin Wang, Yu Cong, Tao Zhang, Xinmiao Liang, Wei Li,* Ning Li.* Production of 1,2-Cyclohexanedicarboxylates from Diacetone Alcohol and Fumarates. ACS Sustainable Chem. Eng. 2019, 7, 2980–2988.

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5. Yancheng Hu^#, Zhitong Zhao^#, Yanting Liu, Guangyi Li, Aiqin Wang, Yu Cong, Tao Zhang, Feng Wang,* Ning Li.* Synthesis of 1,4-Cyclohexanedimethanol, 1,4-Cyclohexanedicarboxylic Acid and 1,2-Cyclohexanedicarboxylates from Formaldehyde, Crotonaldehyde and Acrylate/Fumarate. Angew. Chem. Int. Ed. 2018, 57, 6901-6905.

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4. Yingying Zhao, Chunxiang Wang, Yancheng Hu,* Boshun Wan.* Bronsted Acid-Catalyzed Formal [5+2+1] Cycloaddition of Ynamides and Isoxazoles with Water: Access to Oxygen-Bridged Tetrahydro-1,4-Oxazepines. Chem. Commun. 2018, 54, 3963–3966.

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3. Yancheng Hu, Ning Li,* Guangyi Li, Aiqin Wang, Yu Cong, Xiaodong Wang, Tao Zhang.* Solid Acid-Catalyzed Dehydration of Pinacol Derivatives in Ionic Liquid: Simple and Efficient Access to Branched 1,3-Dienes. ACS Catal. 2017, 7, 2576-2582.

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2. Yancheng Hu, Ning Li,* Guangyi Li, Aiqin Wang, Yu Cong, Xiaodong Wang, Tao Zhang.* Sustainable Production of o-Xylene from Biomass-Derived Pinacol and Acrolein. ChemSusChem. 2017, 10, 2880-2885.

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1. Yancheng Hu, Ning Li,* Guangyi Li, Aiqin Wang, Yu Cong, Xiaodong Wang, Tao Zhang.* Sustainable Production of Pyromellitic Acid with Pinacol and Diethyl Maleate. Green Chem. 2017, 19, 1663-1667.

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